
Here is an updated list for the massive fictional narrative that has made the MCU by far (if not the most) successful franchise in movie history. Over a year after Marvel's Avengers: Endgame hit theatres, this list has grown exponentially since the end of 2017. With that, here is an updated list on the main heroes who were there on the road to Infinity. Thanks for reading.
P.S. - If you're interested in an even bigger & more detailed list that's up to date with the release of Spider-Man: No Way Home, then check out my Marvel Cinematic MULTIVERSE list; It even includes supporting characters and super villains!
Iron Man

Real name: Tony Stark
Portrayed by: Robert Downey Jr.
First Appearance: Iron Man (2008) Directed by Jon Favreau
Last Appearance: Avengers: Endgame (2019) Directed by Joe & Anthony Russo
Powers: Genius, billionaire, playboy, philanthropist
Team Affiliations: Avengers
-Deceased
War Machine

Real name: James "Rhodey" Rhodes
Portrayed by: Don Cheadle (replaced Terrence Howard as of Iron Man 2)
First Appearance: Iron Man (2008)
Last Appearance: Avengers: Endgame (2019)
Powers: Iron Man Armour Technology/Experienced Marine/Aviator
Team Affiliations: US Department of Defence, US Marine Corps, S.H.I.E.L.D, Avengers
Hulk

Real name: Bruce Banner
Portrayed by: Mark Ruffalo (replaced Edward Norton as of The Avengers)
First Appearance: The Incredible Hulk (2008) Directed by Louis Leterrier
Last Appearance: Avengers: Endgame (2019)
Powers: Super strength from gamma radiation/scientist (Banner)
Team Affiliations: Avengers, Revengers
Black Widow

Real name: Natasha Romanoff
Portrayed by: Scarlett Johansson
First Appearance: Iron Man 2 (2010) Directed by Jon Favreau
Last Appearance: Avengers: Endgame (2019)
Powers: Expert martial artist/master in covert art
Team Affiliations: S.H.I.E.L.D, Avengers
-Deceased
Thor

Real name: Thor Odinson
Portrayed by: Chris Hemsworth
First Appearance: Thor (2011) Directed by Kenneth Branagh
Last Appearance: Avengers: Endgame (2019) Directed by Taika Waititi
Powers: Super strength, speed, agility, controls thunder/lighting
Team Affiliations: Avengers, Revengers
Captain America

Real name: Steve Rogers
Portrayed by: Chris Evans
First Appearance: Captain America: The First Avenger (2011) Directed by Joe Johnston
Last Appearance: Avengers: Endgame (2019)
Powers: Superhuman strength, speed, agility, endurance
Team Affiliations: US Army, Avengers, S.H.I.E.L.D
-Retired
The Winter Soldier

Real name: James Buchanan "Bucky" Barnes
Portrayed by: Sebastian Stan
First Appearance: Captain America: The First Avenger (2011)
Last Appearance: Avengers: Endgame (2019)
Powers: Enhanced strength, speed, reflexes, healing, stamina and agility
Team Affiliations: US Army, Hydra
Hawkeye

Real name: Clint Barton
Portrayed by: Jeremy Renner
First Appearance: Thor (2011)
Last Appearance: Avengers: Endgame (2019)
Powers: Master archer, marksman, expert tactician, acrobat and hand-to-hand combatant
Team Affiliations: S.H.I.E.L.D, Avengers
Falcon

Real name: Sam Wilson
Portrayed by: Anthony Mackie
First Appearance: Captain America: The Winter Soldier (2014) Directed by Joe & Anthony Russo
Last Appearance: Avengers: Endgame (2019)
Powers: Mechanical wings, master pilot, expert acrobat and hand-to-hand combatant
Team Affiliations: US Army, S.H.I.E.L.D, Avengers
Guardians of the Galaxy

I decided to group this whole team into one listing since they have stuck together since becoming the Guardians of the Galaxy.
Names: Star Lord, Gamora, Rocket, Groot, Drax, Mantis, Nebula
Portrayed by: Chris Pratt, Zoe Saldana, Bradley Cooper, Vin Diesel, Dave Bautista, Pom Klementieff & Karen Gillan - respectively
First Appearance: Guardians of the Galaxy (2014) Directed by James Gunn
Mantis first appears in Guardians of the Galaxy Vol. 2 (2017) Directed by James Gunn
Powers: Tech/Alien
Team Affiliations: Guardians of the Galaxy
Scarlet Witch

Real name: Wanda Maximoff
Portrayed by: Elizabeth Olsen
First Appearance: Captain America: The Winter Soldier (2014)
Last Appearance: Avengers: Endgame (2019)
Powers: Telekinesis, telepathy, and energy manipulation (Mind stone)
Team Affiliations: Avengers
Vision

Portrayed by: Paul Bettany
First Appearance: Avengers: Age of Ultron (2015) Directed by Joss Whedon
Last Appearance: Avengers: Infinity War (2018)
Powers: Super strength, intangibility flight, energy blasts, technology interactivity (Mind stone holder)
Team Affiliations: Avengers
-Deceased
Ant-Man

Real name: Scott Lang
Portrayed by: Paul Rudd
First Appearance: Ant-Man (2015)
Last Appearance: Avengers: Endgame (2019)
Powers: Pym shrink/enlarge technology
Team Affiliations: None
Wasp

Real name: Hope Van Dyne
Portrayed by: Evangeline Lilly
First Appearance: Ant-Man (2015)
Last Appearance: Avengers: Endgame (2019)
Powers: Pym shrink/enlarge technology, flight
Team Affiliations: None
Black Panther

Real name: T'Challa
Portrayed by: Chadwick Boseman
First Appearance: Captain America: Civil War (2016)
Last Appearance: Avengers: Endgame (2019)
Powers: Superhuman strength, speed, reflexes, agility, stamina, endurance, durability, and senses, genius-level intellect, master martial artist, tactician, strategist, vibranium armoured suit
Team Affiliations: None
Spider-Man

Real name: Peter Parker
Portrayed by: Tom Holland
First Appearance: Captain America: Civil War (2016)
Last Appearance: Spider-Man: Far from Home (2019)
Powers: Superhuman strength, speed, reflexes, agility, stamina, endurance, durability, and senses, Iron Man tech Spider-suit, webs
Team Affiliations: Avengers
Doctor Strange

Real name: Stephen Strange
Portrayed by: Benedict Cumberbatch
First Appearance: Doctor Strange (2016)
Last Appearance: Avengers: Endgame (2019)
Powers: Mystic energy, magic spells, magic tools (sling ring)
Team Affiliations: None
Captain Marvel

Real name: Carol Danvers
Portrayed by: Brie Larson
First Appearance: Captain Marvel (2019) Directed by Anna Boden/Ryan Fleck
Last Appearance: Avengers: Endgame (2019)
Powers: Flight, superhuman strength, photon energy
Team Affiliations: US Air Force
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